Saturday, February 4, 2017

Polychrome makes sensitizers

Polychrome makes sensitizers         By Mr. Bob Gumbinner

On the Newark property of Cellomer, we had a building in which we made the negative plate sensitizer, formaldehyde-diazoparadiphenylamine complex. This was made by reacting paraformaldehyde with the diazoparadiphenylamine in concentrated sulphuric acid at 35°F and dropping it on ice to make a 2% solution of the diazo which was filtered. The diazo was precipitated by adding a saturated solution of zinc chloride. This was filtered and dried. By precipitating the diazo from the 2% solution with MS-40 we obtained an organic soluble diazo. We started to make Polychrome Fotomer subtractive plates by mixing this diazo with epoxy resins. To increase the length of the press run we tried a number of different formulations. Bill Rowe developed a polyester resin which when added to the epoxy resins and a polyvinyl formal resin gave us an excellent presensitized subtractive plate. One feature that we were able to obtain that our competitors didn’t was that when the coating was removed from the non-image area of the plate it did not particulate and gum up so that when the plates were develop by passing through a machine with a brush to remove the non-exposed coating we did not need to use a filter. When our plant in Clark was ready for occupancy, Bill Rowe moved his laboratory there since he lived in the next town, Westfield, New Jersey.